

Image poisoning’s general principle is to change pixels in a way were our eye can’t notice, but that screw up the labeling by LLMs.
You can probably try to apply the same principle, poison the PDF in a way that only humans can read it.
Thing is, I assume you distribute your content on PDFs to make the content accessible to humans. That usually means having the text embedded for easy copy-paste and similar methods. Poisoning these might end up being counterproductive for your objective.
All this to say that No, I have no idea of a poisoning algorithm for PDFs

Have you considered a torrent based solution?
Setup a torrenting server hosted online somewhere with fast speeds (e.g. Netherlands), sync it with gdrive, create a torrent for your books, and “download” your books to the toreenting machine.
This approach won’t help with upload speed, but it should help with reliability/continuity. As long as you seed from your home computer, your books will eventually make it into your gdrive.
Although with this setup it might be easier to just torrent the ebooks to the online server from sources other than yourself.